Resonance Raman Spectra Interpretation by Molecular Coherent State Representation
作者:
N.Yu. Trifonov,
期刊:
Journal of Modern Optics
(Taylor Available online 1992)
卷期:
Volume 39,
issue 1
页码: 21-34
ISSN:0950-0340
年代: 1992
DOI:10.1080/713823352
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
In this paper the problem of exact summation over vibrational states of intermediate electronic level excited by resonance Raman scattering in a molecular system with an arbitrary number of vibrational modes is solved with the help of the coherent state representation. For matrix elements of the resonance Raman (RR) amplitude the expressions in the form of an integral and multiple series as well as recurrence relations are obtained. The interpretation of RR spectra of linear-chain mixed-valence platinum complexes is given as an illustration.
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