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Transition State Theory in Isotope and Radiation Chemistry

 

作者: W. Stiller,   R. Haberlandt,   Sz. Vass,  

 

期刊: Isotopenpraxis Isotopes in Environmental and Health Studies  （Taylor Available online 1985）
卷期: Volume 21, issue 12  

页码: 409-412

 

ISSN:0021-1915

 

年代: 1985

 

DOI:10.1080/10256018508623567

 

出版商: Taylor & Francis Group

 

关键词: gases;ions;isotopes;isotope effects;kinetics;radiation chemistry;reaction kinetics

 

数据来源: Taylor

 

摘要:

A short survey of the history of the transition state theory (TST) including new developments is given. In isotope chemistry reaction-kinetic isotope effects can be calculated via TST using the concept of molecular partition functions. Several examples are given. In radiation chemistry TST is applied on particular to ionic reactions. The general procedure is exemplified by ion-molecule reactions.

 

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