Density Functional Theory of Liquid Crystal Phases
作者:
A. Poniewierski,
T.J. Sluckin,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1992)
卷期:
Volume 212,
issue 1
页码: 61-75
ISSN:1058-725X
年代: 1992
DOI:10.1080/10587259208037248
出版商: Taylor & Francis Group
关键词: phase transitions;smectics;theory;density functional
数据来源: Taylor
摘要:
A general discussion is given of the application of density functional theory of liquids to liquid crystal problems, with particular emphasis to the onset of smectic phases. Hard particle systems have long been used as useful paradigms of liquid crystal behaviour. In this paper we also present recent work on the phase diagram of hard spherocylinders, using a non-local density functional theory of a kind which has been successful in the study of hard sphere thermodynamics. We also discuss the effect of electric quadrupolar forces on the phase diagram of Onsager-like systems.
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