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Density Functional Theory of Liquid Crystal Phases

 

作者: A. Poniewierski,   T.J. Sluckin,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1992)
卷期: Volume 212, issue 1  

页码: 61-75

 

ISSN:1058-725X

 

年代: 1992

 

DOI:10.1080/10587259208037248

 

出版商: Taylor & Francis Group

 

关键词: phase transitions;smectics;theory;density functional

 

数据来源: Taylor

 

摘要:

A general discussion is given of the application of density functional theory of liquids to liquid crystal problems, with particular emphasis to the onset of smectic phases. Hard particle systems have long been used as useful paradigms of liquid crystal behaviour. In this paper we also present recent work on the phase diagram of hard spherocylinders, using a non-local density functional theory of a kind which has been successful in the study of hard sphere thermodynamics. We also discuss the effect of electric quadrupolar forces on the phase diagram of Onsager-like systems.

 

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