Structure of fluid interfaces: an integral equation study
作者:
Stanislav Iatsevitch,
Frank Forstmann,
期刊:
Molecular Physics
(Taylor Available online 2000)
卷期:
Volume 98,
issue 17
页码: 1309-1322
ISSN:0026-8976
年代: 2000
DOI:10.1080/002689700413569
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
We develop a method for treating an interface between coexisting fluid phases to study its structure and thermodynamical properties. Our approach includes calculated correlation functions. Approximations are intrinsically optimized. The method is successfully applied to the liquid vapour surface of a Lennard-Jones fluid, to the liquid–liquid interface of a demixing system and to the surface of a Stockmayer liquid towards vapour. In all cases we compare our results to simulations. The agreement with simulation results demonstrates the reliability of our approximations and shows that the technique we applied provides a powerful and robust method for studying inhomogeneous fluids.
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