Effect of Several Heavy-Atoms on Room Temperature Phosphorescence of Biphenyl and Several Polychlorinated Biphenyls on Filter Paper
作者:
I.M. Khasawneh,
M. Chamsaz,
J.D. Winefordner,
期刊:
Analytical Letters
(Taylor Available online 1988)
卷期:
Volume 21,
issue 1
页码: 125-144
ISSN:0003-2719
年代: 1988
DOI:10.1080/00032718808082029
出版商: Taylor & Francis Group
关键词: Room Temperature Phosphorescence;Heavy-Atom;Biphenyl;Polychlorinated Biphenyls
数据来源: Taylor
摘要:
Room temperature phosphorescence (RTP) signals on filter paper depend on experimental conditions including type of filter paper, drying and cooling times of the paper after spotting the sample, and type and concentration of heavy-atom present. RTP of biphenyl, as a model compound, on six filter papers using eleven different heavy-atoms is examined. The highest RTP signal is observed when S&S 903 filter paper is used and dried in an oven at 110°C for 10 min and cooled in a nitrogen gas stream for 10 min. RTP characteristics of several polychlorinated congeners and mixtures are presented without and with the presence of different heavy-atoms; RTP intensities increase and the limits of detection decrease. Lifetimes of all compounds exhibiting RTP are measured. An RTP comparison study of several PCBs on two different types of filter papers is also reported.
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