The dielectric relaxation spectra of a system of lithium borosilicate glasses have been investigated over the frequency range 0.01 cps to 500 kc and temperatures between 25°–350°C. The spectra of the samples exhibit well‐defined peaks in the dielectric loss factor and dispersion in the dielectric constant. The activation energies associated both with the lithium ion mean relaxation frequency and the lithium ion dc conductivity (zero frequency conductivity) are constant with temperature; their difference for each sample appears to be an indication of the distribution of activation energies of the sample. The experimental data show that an analytical function proposed by K. W. Wagner adequately describes the distribution of relaxation times associated with the lithium ion relaxation process in the glass network. The distribution originates from a spread in activation energies for low lithium concentrations and a spread in the period of vibration of the lithium ions about their equilibrium position for higher concentrations.