Carbon-13 NMR Spectroscopy High-Resolution Methods and Applications in Organic Chemistry and Biochemistry Third, completely revised edition by E. Breitmaier and W. Voelter 1987. XVI, 515 pages with 129 figures and 158 tables. Hardcover. f 88.00. ISBN 3-527-26466-3 Carbon-13 NMR Spectral Data A Living COM-Microfiche Collection of Reference Material Fourth edition by W. Bremser, L. Ernst, W. Fachinger, R. Gerhards, A. Hardt and P. M. E. Lewis 1987. 58108 spectra of 48357 compounds on 235 micro- fiches with a 35-page introductory text. For new customers: Complete set: 3 ring binders containing 11 pages of housing frames. f 1467.00. ISBN 3-527-26198-2 For previous subscribers: 1 ring binder containing 4 addi- tional pages of housing frames. f 880.00. ISBN 3-527-25899-X Biomedical Magnetic Resonance Imaging Prlnciples, Methodology and Applications edited by F.W. Wehrli, D. Shaw and J. B. Kneeland 1988. XVIII, 601 pages with 313 figures and 30 tables. Hardcover. f 69.00. ISBN 3-527-26701 -8 Series: Methods in Stereochemical Analysis Stereochemical Applications of NMR Studies in Rigid Bicyclic Systems Volume 1: by A. P. Marchand 1982. XI, 231 pages with 4 figures and numerous tables. Hardcover. f 103.00. ISBN 3-527-25976-7 Volume 2 Carbon-Carbon and Carbon-Proton NMR Couplings Applications to Organic Stereochemistry and Conformational Analysis by J. L. Marshall 1983. VIII, 241 pages with 9 figures and numerous tables. Hardcover. f 64.00. ISBN 3-527-25977-5 Volume 3 Stereochemistry and Reactivity of Systems Containing n Electrons edited by W.H. Watson 1983. XIV, 439 pages. Hardcover. f 59.00. ISBN 3-527-261 15-X To order please contact your bookseller or VCH Publishers (UK) Ltd.. 8 Wellington Court. Wellington S t , GB-Cambridge CB1 1HW VCH Verlagsgesellschaft. P 0. Box 1011 61, D-6940 Wemheim VCH Verlags-AG. Hardstrasse 10, P.O. Box, CH-4020 Basel . VCH Publishers. Sulte 909.220 East 23rd Street, New York, NY 10010-4606, USA Volume 4 Applications of Dynamic NMR Spectroscopy to Organic Chemistry by M. Oki 1985. XII, 423 pages with 8 figures and 109 tables. Hardcover. f 77.00. ISBN 3-527-26166-4 Volume 6 Applications of NMR Spectroscopy to Problems in Stereochemistry and Conformational Analysis edited by Y. Takeuchi and A. P. Marchand 1986. IX. 221 pages with 52 figures. Hardcover. f 49.75. ISBN 3-527-26145-1 Volume 7 High-Resolution NMR Spectroscopy of Synthetic Polymers in Bulk edited by R.A. Komoroski 1986. XI. 379 pages with 47 figures. Hardcover. f 68.00. ISBN 3-527-26464-7 Volume 8 Phosphorus-31 NMR Spectroscopy in Stereochemical Analysis Organic Compounds and Metal Complexes edited by J. G. Verkade and L. D. Quin 1987. XVI, 717 pages with 74 figures. Hardcover. f 95.00. ISBN 3-527-26465-5 Volume 5 Lanthanide Shift Reagents in Stereo- chemical Analysis edited by T. C. Morrill 1987. XIII, 193 pages with 43 figures and 17 tables. Hardcover. f 42.25. ISBN 3-527-26167-2 Volume 9 Two- Dimensional NMR Spectroscopy Applications for Chemists and Biochemists edited by W. A. Croasmun and R. M. K. Carlson 1987. XVIII, 51 1 pages with 192 figures and 32 tables.Hardcover. f 78.95. ISBN 3-527-26528-7 Sterling prices subject to change without noticeNuclear Magnetic Resonance Vol 17 Specialist Periodical Report Senior Reporter: 0 A Webb, UniverSi2g ofSumq ISBN: 0 85186 402 3 Hardcover 546pp Rice: jZl10.00 ($239.00) Nuclear Magnetic Resonance Volume 17 provides a review of the literature published between June 1986 and May 1987. Brief Contents: Theoretical and Physical Aspects of Nuclear Shielding * Applications of Nuclear Shielding Theoretical Aspects of Spin-Spin Couplings Nuclear Spin Relaxation in Liquids Solid Sate NMR Mutiple Pulse NMR Natural Macromolecules Synthetic Macromolecules Conformational Analysis * Nuclear Magnetic Resonance of Living Systems Oriented Molecules Heterogeneous Systems Nuclear Magnetic Resonance Volume 17 contains a foreword by the senior reporter and a detailed contents list.Each chapter includes extensive references. ROYAL CHEMISTRY Information Services To order or for further information please contact: Alison Hibberd, Sales and Promotion Dept., Royal Soclety of Chemistry, The University, Nottlngham NG7 2RD, UK. Telephone (0602) 5074 1 1. Telex: 37488ISSN 0300-9238 JCFTAR 84(11) 3649-4201 (1 988) 3649 3673 369 1 3713 373 1 3747 376 1 3777 3785 3803 382 1 3857 JOURNAL OF THE CHEMICAL SOCIETY Faraday Transactions I Physical Chemistry in Condensed Phases Professor Robin Harris of Durham University was invited to contribute a keynote paper on the general theme of Nuclear Magnetic Resonance Spectroscopy in Solids. He was supported by a group of research workers who submitted original papers on cognate subjects.All these papers have now been refereed, and are collected at the beginning of the present issue. CO N T E NTS Perspectives in High-resolution Solid-state Nuclear Magnetic Resonance, with Emphasis on Combined Rotation and Multiple-pulse Spectroscopy R. K. Harris, P. Jackson, L. H. Merwin, B. J. Say and G. Hagele Carbon- 1 3 Chemical-shift Tensors in Single-crystal Methoxybenzenes C. M. Carter, J. C. Facelli, D. W. Alderman, D. M. Grant, N. K. Dalley and B. E. Wilson Enhancement of the Effect of Small Anisotropies in Magic-angle Spinning Nuclear Magnetic Resonance D. P. Raleigh, A. C. Kolbert, T. G. Oas, M. H. Levitt and R. G. Griffin Spectral Spin Diffusion in Polycrystalline Solids under Magic-angle Spinning A.Kubo and C. A. McDowell The Nuclear Magnetic Resonance of 12'Xe trapped in Clathrates and some other Solids J. A. Ripmeester, C. I. Ratcliffe and J. S. Tse Quadrupole Nutation Nuclear Magnetic Resonance in Solids R. Janssen and W. S. Veeman Deuterium Quadrupole-echo Studies of Molecular Motion in a Biphenyl+- Cyclodextrin Clathrate Highly Resolved Solid-state Proton Magnetic Resonance Studies of Zeolites H. Pfeifer Nuclear Magnetic Resonance Study of Pt-Rh Bimetallic Clusters 2. Wang, J-P. Ansermet, C. P. Slichter and J. H. Sinfelt Peptide Backbone Conformation by Solid-state Nuclear Magnetic Resonance Spectroscopy Some New Developments in Solid-state Nuclear Magnetic Resonance Spectro- scopic Studies of Lipids and Biological Membranes, including the Effects of Cholesterol in Model and Natural Systems J.Forbes, J. Bowers, X. Shan, L. Moran, E. Oldfield and M. A. Moscarello 'H Nuclear Magnetic Resonance and Spin-Lattice Relaxation in Solid, High- density Polyethylene A. D. Ronemus, R. R. Vold and R. L. Vold P. L. Stewart, R. Tycko and S. J. Opella K. J. Packer, I. J. F. Poplett and M. J. Taylor 3865 3877 3885 Mixtures of Benzene and Chloroform near a Silica with Grafted Poly(ethy1ene oxide) Chains H. B. Ouada, H. Hommel A. P. Legrand, H. Balard and E. Papirer Viscosity of Solutions of NaI and CaCl, in Water-Ethanol and of NaI in Water-tetrahydro furan Mixtures B. Nowicka, A. Kacperska, J. Barczynska, A. Bald and S. Taniewska-Osinska Application of Kirkwood-Buff Theory to Enthalpies of Transfer and Expansibilities of Solutes in Binary Solvent Mixtures K.E. Newman 120-2389 1 3905 3917 3927 394 1 395 1 396 1 3973 3983 399 1 4013 4023 403 3 4043 4049 406 1 4073 4087 4097 4105 41 15 4125 4137 Con tents A Study of the Surface Chemistry of Anion-exchange Resins using X-Ray Photoelectron Spectroscopy G. C. Allen, N. R. Holmes, B. J. Lee and R. R. Harries Studies of Architecture of Moo,-TiO, Catalysts T. Machej, B. Doumain, B. Yasse and B. Delmon The Influence of Crown Ethers on Cation Migration Processes. Part 6.-The 174-Naphthoquinone Radical Anion N. J. Flint and B. J. Tabner Diffusion of H+ and OH- in Porous Solids J. J. Lewnard, E. E. Petersen and C. J. Radke Electrochromism of a Conducting Polypyrrole-Phosphotungstate Composite Electrode T. Shimidzu, A.Ohtani, M. Aiba and K. Honda Surface Solubilization B-Y. Zhu, X. Zhao and T. Gu An Electron Spin Resonance Study of Charge-carrier Stabilization in ZnO A. R. Gonzalez-Efipe and J. Soria Spectrophotometric Study of the Pseudotetrahedral Bromocomplexes of Cobalt(r1) in Hexamethylphosphoramide Solution M. Pilarczyk, W. Gryzb- kowski and L. Klinszporn A Theoretical Study of the Kinetics of Deoxyhaemoglobin S Aggregation R. P. Hazoume and N. M. Hounkonnou Heat Capacity and Corresponding States in Alkan- 1 -01-n-Alkane Systems L. Andreoli-Ball, D. Patterson, M. Costas and M. Caceres-Alonso Ionic Solvation. Part 4.--Copper(r) Solvation. Disproportionation and Halide- complex Formation in Propylene Carbonate A. Lewandowski The Kinetics of Cathodic Generation of R,N(Hg,) C.M. Ryan, V. SvetliW and E. Kariv-Miller Determination of Diffusion Coefficients and Effective Charge Numbers of Lignosulphonate. Influence of Ionic Strength and the Valency of t.he Counter- ion A-K. Kontturi Diffusion Coefficients and Effective Charge Numbers of Lignosulphonate. Influence of Temperature A-K. Kontturi Characterisation of Crystalline UO, oxidised in 1 Torr of Oxygen at 25,225 and 300 "C. Part 1.-X-Ray Photoelectron Spectroscopy G. C. Allen, P. A. Tempest and J. W. Tyler Characterisation of Crystalline UO, oxidised in 1 Torr of Oxygen at 25, 225 and 300 "C. Part 2.-X-Ray Diffraction and Scanning Electron Microscopy G. C. Allen, P. A. Tempest and J. W. Tyler Excess Heat Capacities and Excess Volumes of n-Alkane Mixtures D. Apam- Martinez and A.Trejo Calorimetric Study of Non-ionic Surfactants. Enthalpies and Heat-capacity Changes for Micelle Formation in Water of C,E, and Triton X-100 and Micelle Size of C,E, B. Andersson and G. Olofsson Reduction-Agglomeration Model for Metal Dispersion in Platinum-exchanged NaX Zeolite D. Exner, N. Jaeger, A. Kleine and G. Schulz-Ekloff Radiation Damage in Organic Phosphates. Crystal Structure of 3-0-Dip- henoxyphosphoryl- 172-U-isopropylidene 5-O-Trityl-a-~-ribofuranose and an Electron Spin Resonance Study of the X-Irradiated Single Crystal T. Berclaz, G. Bernardinelli, A. CClalyan-Berthier and M. Geoffroy Mechanism of Deuterium Addition and Exchange of Propene over Silica- supported Gold and Silver Catalysts The Excess Surface Tensions of Simple Binary Mixtures Acidic Properties of Molybdenum Oxide highly dispersed on Titania Miyata, T.Mukai, T. Ono and Y. Kubokawa s. Naito and M. Tanimoto J. S. Rowlinson H.Con tents 4145 4 157 4 16 1 4 169 Coupling of Free Energies in the Formation of Intermediates during the Catalytic Decomposition of H,O, Kinetics of a-Hydroxyl Elimination from [(H20)),CuiiCH2C(CH,),0H]+ in Aqueous Solution. A Pulse-radiolysis Study H. Cohen and D. Meyerstein Crystal-like Structures of Deionized Polystyrene Spheres at Interfaces with Quartz, Air, n-Hexane, Polystyrene and Poly(methy1 methacrylate) T. Okubo Kerr Constants and Dielectric Polarisations of Amides and Thioamides in Water and Dioxane Solutions M. J. Aroney, K. M. Dowling, E. Patsalides, R. K. Pierens and S. W. Filipczuk Photocatalytic Oxidation of Iodide Ions by Titanium Dioxide P. R. Harvey and R. Rudham Adsorption of Methylene Blue from Aqueous Solutions by ZSM-5-Type Zeolites and Related Silica Polymorphs M. L. Kremer 4181 419 1 G. P. Handreck and T. D. SmithCon tents 4145 4 157 4 16 1 4 169 Coupling of Free Energies in the Formation of Intermediates during the Catalytic Decomposition of H,O, Kinetics of a-Hydroxyl Elimination from [(H20)),CuiiCH2C(CH,),0H]+ in Aqueous Solution. A Pulse-radiolysis Study H. Cohen and D. Meyerstein Crystal-like Structures of Deionized Polystyrene Spheres at Interfaces with Quartz, Air, n-Hexane, Polystyrene and Poly(methy1 methacrylate) T. Okubo Kerr Constants and Dielectric Polarisations of Amides and Thioamides in Water and Dioxane Solutions M. J. Aroney, K. M. Dowling, E. Patsalides, R. K. Pierens and S. W. Filipczuk Photocatalytic Oxidation of Iodide Ions by Titanium Dioxide P. R. Harvey and R. Rudham Adsorption of Methylene Blue from Aqueous Solutions by ZSM-5-Type Zeolites and Related Silica Polymorphs M. L. Kremer 4181 419 1 G. P. Handreck and T. D. Smith