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Synthesis and Molecular Structure of the Amido-Bridged Dinuclear Rhodium Complex [Cp*Rh{μ2-(NH)2C10H6-2,3}(μ2-Cl)RhCp*][PF6] (Cp* = η5-C5Me5)

 

作者: Hiroyuki Matsuzaka,   Teruo Kamura,   Ko Ariga,   Takashi Okubo,   Tomohiko Ishii,   Masahiro Yamashita,   Mitsuru Kondo,   Susumu Kitagawa,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 342, issue 1  

页码: 1-6

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008038237

 

出版商: Taylor & Francis Group

 

关键词: dinuclear complex;rhodium;bridging amido ligand;X-ray structure

 

数据来源: Taylor

 

摘要:

Reaction of [Cp*RhCl2]2(1) with (LiNH)2C10H6-2,3 gives the mononuclear species Cp*Rh(NH)2C10H6-2,3 (3), which is selectively converted to the amido-bridged dinuclear Rh(III) complex [Cp*Rh{μ2-(NH)2C10H6-2,3}(μ2-Cl)RhCp*]PF6(4; Cp* = η5-C5Me5) upon treatment with1/AgPF6in acetone. The molecular structure of4has been determined by X-ray crystallography.

 

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