Spectrophotometric Determination of Trace Amounts of Mercury(II) in Waste Water with p-Azobenzenediazoaminoazobenzene Sulfonic Acid
作者:
JIANG Wanquan,
ZHU Yurui,
JIN Gu,
WU Guohua,
期刊:
Analytical Letters
(Taylor Available online 1996)
卷期:
Volume 29,
issue 12
页码: 2221-2226
ISSN:0003-2719
年代: 1996
DOI:10.1080/00032719608002243
出版商: Taylor & Francis Group
关键词: Mercury spectrophotometry triazene;p-azobenzenediazoaminoazobenzene sulfonic acid
数据来源: Taylor
摘要:
A new method for the direct determination of trace mercury in aqueous solution with high selectivity and sensitivity is reported. In the presence of Triton X-100 and NH3.NH4Cl medium, a new chromogenic reagent p-azobenzenediazo- aminoazobenzene sulfonic acid (ADAAS) forms a red complex with mercury(II). The molar absorptivity is 1.76×105l. mol−1cm−1at 528 nm. Beer's law is obeyed in the range of 6.0×10−8- 6.0×10−6mol/L for Hg(II). Only cadmium interferes in the determination of mercury, and it can be eliminated by masking with nitrilotriacetic acid. The proposed method has been successfully used for the determination of trace amounts of mercury in waste water.
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