Liquid-Liquid Equilibrium of Polydisperse Copolymer Solutions. Multivariate Distribution Functions in Continuous Thermodynamics
作者:
MargitT. Rätzsch,
Horst Kehlen,
Dieter Browarzik,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1985)
卷期:
Volume 22,
issue 12
页码: 1679-1690
ISSN:0022-233X
年代: 1985
DOI:10.1080/00222338508063365
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
In addition to the usual polydispersity with respect to molar mass, copolymers show chemical polydispersity. Thus, the species present may not be adequately characterized by a single variable, and a divariate distribution function has to be applied for describing the composition of the copolymer. In continuous thermodynamics, such continuous distribution functions are used directly (without splitting into pseudocomponents) for describing the composition of complex multicomponent systems. Whereas until now usually only one distribution variable has been used in continuous thermodynamics, consideration of copolymers requires an extension to divariate distribution functions. Continuous thermodynamics is generalized to divariate distribution functions in this paper. The liquid-liquid equilibrium of copolymer solutions is considered as a specific example.
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