Raman and infrared study of reorientational dynamics in trifluorobenzene
作者:
P. Yuan,
A. F. T. Chen,
M. Schwartz,
期刊:
Journal of Raman Spectroscopy
(WILEY Available online 1989)
卷期:
Volume 20,
issue 1
页码: 27-30
ISSN:0377-0486
年代: 1989
DOI:10.1002/jrs.1250200106
出版商: John Wiley&Sons, Ltd.
数据来源: WILEY
摘要:
AbstractThe Raman spectral bandwidths of twoA1′ vibrations of 1,3,5‐trifluorobenzene (TFB) were measured in the neat liquid as a function of temperature and in the solvents CH2Cl2and CS2. The Raman and IR linewidths of twoE′ modes were also measured in solution. Derived values of the two rotational diffusion constants,D⊥andD∥, were compared with the predictions of several current theories. It was observed that the Hynes–Kapral‐Weinberg (HKW) theory is superior to both the microviscosity–free rotor and Hu–Zwanzig ‘slip’ models of reorientational diffusion. Calculated values ofD⊥andD∥for TFB in solution using the HKW model are in excellent agreement with the experimentally mea
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