Copolymerization with Depropagation
作者:
K.F. O'driscoll,
F.P. Gasparro,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1967)
卷期:
Volume 1,
issue 4
页码: 643-652
ISSN:0022-233X
年代: 1967
DOI:10.1080/10601326708054001
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Free-radical copolymerizations of styrene with α-methylstyrene and methyl methacrylate and of acrylonitrile with α-methylstyrene have been carried out in the approximate regions of the ceiling temperatures of α-methylstyrene and methyl methacrylate. A theoretical treatment of copolymerization emphasizing the thermodynamic reversibility of particular propagation reactions has been compared with a kinetic treatment of copolymerization which emphasizes penultimate unit effects on the same propagation reactions. The former is found to adequately describe experimental copolymer composition data over a wide range of temperatures and over the complete range of monomer feed composition.
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