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Approach to thermal equilibrium in a system with adiabatic constraints

 

作者: Bruno Crosignani,   Paolo Di Porto,   Mordechai Segev,  

 

期刊: American Journal of Physics  (AIP Available online 1996)
卷期: Volume 64, issue 5  

页码: 610-613

 

ISSN:0002-9505

 

年代: 1996

 

DOI:10.1119/1.18163

 

出版商: American Association of Physics Teachers

 

关键词: THERMAL EQUILIBRIUM;ADIABATIC PROCESSES;CONSTRAINTS;ENTROPY;KINETICS;PISTONS;05.70

 

数据来源: AIP

 

摘要:

The problem of prediction of the equilibrium state in an isolated composite system with an adiabatic internal wall is a delicate problem, whose solution is easily seen to be not entirely determined in the frame of elementary thermodynamics. We show how this indeterminacy can be removed by introducing a suitable kinetic model, in which the influence of the finite velocity of the wall on the change of momentum of the gas molecules impinging on it plays a relevant role. An interesting feature of the entropy behavior of the system is discussed.

 

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