Characteristic time for self‐diffusion coefficient of linear polymers in semidilute solutions
作者:
Yoshiaki Takahashi,
Masayoshi Yamaguchi,
Ichiro Noda,
期刊:
Journal of Rheology
(AIP Available online 1993)
卷期:
Volume 37,
issue 3
页码: 569-569
ISSN:0148-6055
年代: 1993
DOI:10.1122/1.550382
出版商: The Society of Rheology
关键词: Characteristic time;Self‐diffusion coefficient;Weight‐average relaxation time;Semidilute region;Reptation model;POLYMERS;SOLUTIONS;SELF−DIFFUSION;RELAXATION TIME;VISCOELASTICITY
数据来源: AIP
摘要:
The concentration dependence of characteristic time τrfor self‐diffusion coefficientDsof linear polymers in good solvents was discussed in comparison with that of the weight average relaxation time τwfor viscoelastic properties. Similarities were found for the concentration regions of τrand τw , and also for the concentration dependences of τ’s in the respective regions. On the basis of the similarities, it is pointed out that almost all theDsdata of polymers at finite concentrations so far published should not be discussed in terms of the reptation model since the solutions are not regarded as those in the well entangled regions.
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