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Another Look at Long-Chain Branching

 

作者: R.V. Mullikin,   GeorgeA. Mortimer,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1970)
卷期: Volume 4, issue 7  

页码: 1495-1505

 

ISSN:0022-233X

 

年代: 1970

 

DOI:10.1080/00222337008069365

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Long-chain branching can occur during radical polymerization and is especially important for polyethylene. An improved method of calculating the effect of long-chain branching on molecular weight distribution is presented. This method uses a probability treatment. The results are more consistent with both kinetic theory and experimental data than the results of previous long-chain branching calculations. In contrast to previous calculations, the present work shows that generation cannot occur from long-chain branching alone.

 

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