Effects of deuteriation on ZFS and sublevel decay rates of3ππ* benzaldehyde
作者:
Yoshihiro Hirata,
Noboru Hirota,
期刊:
Molecular Physics
(Taylor Available online 1980)
卷期:
Volume 39,
issue 1
页码: 129-141
ISSN:0026-8976
年代: 1980
DOI:10.1080/00268978000100111
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
We have investigated deuterium effects on the ZFS and the sublevel decay rates of3ππ* benzaldehyde in three different hosts. It was found that deuteriation of the formyl hydrogen reduces D considerably in acetophenone and 1,4-dichlorobenzene hosts. This effect is explained in terms of the changes in the3ππ*-3nπ* energy separations.
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