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Melt Rheology and Morphology of Nitrile Rubber and Ethylene-Vinyl Acetate Copolymer Blends

 

作者: Hima Varghese,   J.S. Anand,   K. Ramamurthy,   R. Janardhan,   S.S. Bhagawan,   Sabu Thomas,  

 

期刊: Polymer-Plastics Technology and Engineering  (Taylor Available online 1999)
卷期: Volume 38, issue 2  

页码: 319-339

 

ISSN:0360-2559

 

年代: 1999

 

DOI:10.1080/03602559909351581

 

出版商: Taylor & Francis Group

 

关键词: Nitrile rubber;Ethylene-vinyl acetate copolymer;Rheology;Melt viscosity;Shear rate;Shear stress;Morphology

 

数据来源: Taylor

 

摘要:

The melt Theological behavior of nitrile rubber (NBR)/ethylene-vinyl acetate (EVA) copolymer blends was studied with special reference to the effect of the blend ratio, cross-linking systems, and shear rate using a capillary rheometer. At a given shear stress at 90°C, the viscosities of the blends vary slightly with composition. The effect of cross-linking systems [viz., sulfur (S), peroxide (DCP) and mixed (S+DCP) systems] on the viscosity of NBR/EVA blends is negligible. The melt viscosity of the blends decreases with increasing shear rate, showing pseudoplastic behavior. The flow behavior index values also support the pseudoplastic nature of these blends. Various theoretical models were used to predict the melt viscosity of the blends. Parameters such as die swell, principal normal stress difference, recoverable shear strain, and shear modulus were calculated to characterize the melt elasticity of these blends. The melt elasticity of the system was increased by the addition of NBR to EVA. The extrudate deformation at different shear rates was also studied. It was observed that as the shear rate increases, the extrudate surface exhibits a higher degree of deformation. The morphology of the extrudates of the blends at different shear rates has been examined by a scanning electron microscope. The morphology was found to be dependent on the blend ratio and shear rate.

 

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