ACCELERATED CLEAVAGE OF P-NITROPHENYL PICOLINATE CATALYZED BY COPPER(II) AND ZINC(II) COMPLEXES OF D-GLUCOSAMINE SCHIFF BASE IN MICELLAE SOLUTION
作者:
XIANG VAN,
ZENG XIANCHENG*,
CHENG SIQING,
LI YANTUAN,
XIE JIAQING,
期刊:
Journal of Dispersion Science and Technology
(Taylor Available online 2000)
卷期:
Volume 21,
issue 7
页码: 857-867
ISSN:0193-2691
年代: 2000
DOI:10.1080/01932690008913316
出版商: Taylor & Francis Group
关键词: D-glucosamine schiff base;Metal complex;Catalysis;Kinetic;Hydrolysis of p-nitrophenyl picolinate
数据来源: Taylor
摘要:
The hydrolysis of p-nirrophenyl picolinate (PNPP) catalyzed by the Cu(II) and Zn(H) complexes of d-glucosamine schiff base was investigated kinetically by observing the rates of the release of p-nitrophenol in the buffered micellor solution at different pit and 25°C. The scheme for reaction acting mode involving a ternary complex contain ligand, metal ion and substrate in micelle was establish and the reaction mechanisms were discussed The experimental results indicated that the complexes catalyzed efficiently the hydrolysis of PNPP, especially Zn(II) complex. The rate constant kN, which shows the catalytic reactivity of complexes, WBI determined to be 0.4251 s−1far Cu(II) complex at pH 7 60 in micellar solution. The catalytic reactivity of Zn(II) complex were much larger than Cu(II) complex, the kNwas determined to be 3.1914 s−1at same pH value.
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