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Computer simulation of hard-core models for liquid crystals

 

作者: D. Frenkel,  

 

期刊: Molecular Physics  (Taylor Available online 1987)
卷期: Volume 60, issue 1  

页码: 1-20

 

ISSN:0026-8976

 

年代: 1987

 

DOI:10.1080/00268978700100011

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Liquid crystals are usually not thought of as ‘simple’ liquids. Nevertheless, a surprising number of features of liquid crystals can be reproduced in computer simulations of very simple model systems, viz. hard ellipsoids of revolution and parallel spherocylinders. In particular, depending on the density and the shape of the hard-core particles, stable isotropic, nematic, smectic and crystalline phases are found. The existence of hard-core models for liquid crystals is important for two reasons. First of all, they can be used to test molecular theories for the static and dynamic properties of liquid crystals. And secondly, they may provide a starting point for thermodynamic perturbation theories. These hard-core models exhibit large pre-transitional fluctuations in the vicinity of some of the phase transitions, similar to those observed in real mesogens. Examples are given of the ‘experimental’ consequences of nematic and smectic precursor effects.

 

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