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Vibrational spectra and force constants of symmetric tops

 

作者: F. Lattanzi,   C. di Lauro,   H. Bürger,   R. Eujen,   P. Schulz,   S. Cradock,  

 

期刊: Molecular Physics  (Taylor Available online 1984)
卷期: Volume 51, issue 1  

页码: 81-96

 

ISSN:0026-8976

 

年代: 1984

 

DOI:10.1080/00268978400100061

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The infrared spectra of the monoisotopic species H374Ge79Br and H374Ge81Br in the 750–1000 cm-1region covering the vibrationsv2,v5andv3+v6have been recorded with a resolution of 0·04 cm-1and rotationally analysed. In addition, information concerning the hot band (v3+v5) -v3has been obtained and data onv6and (v3+v6) -v3have been used. Fermi resonance betweenv5andv3+v6has been established with |W356| = 4·4067(7)/4·3055(8) cm-1(79/81Br) and the Coriolisx,yresonance linkingv2withv5has been evaluated.

 

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