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Molecular model for cholesteric polymers including biaxiality and chain flexibility

 

作者: L. Varichon,   A.Ten Bosch,  

 

期刊: Liquid Crystals  (Taylor Available online 1993)
卷期: Volume 14, issue 6  

页码: 1635-1644

 

ISSN:0267-8292

 

年代: 1993

 

DOI:10.1080/02678299308027703

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A mean field theory for cholesteric polymers based on the elastic model is presented. The effect of flexibility and the biaxial order and nematic order parameters are studied. The biaxial order and nematic order parameters are increasing functions of chirality and vary slightly with flexibility. Biaxiality is shown to be important for the transition temperature and the cholesteric pitch as well as the latent heat of transition.

 

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