Transitions in High Polymeric Materials
作者:
Rolf Buchdahl,
Lawrence E. Nielsen,
期刊:
Journal of Applied Physics
(AIP Available online 1950)
卷期:
Volume 21,
issue 6
页码: 482-487
ISSN:0021-8979
年代: 1950
DOI:10.1063/1.1699690
出版商: AIP
数据来源: AIP
摘要:
The evidence for and against the interpretation of the ``second‐order'' transition in polymers in terms of a thermodynamic transition of the second order is reviewed and some new experimental data concerning transition in mixtures of polymers are presented. It is shown that the relaxation theory is insufficient to explain the transition, as observed by mechanical, electrical and thermal measurements. The usual objections which are raised against the assumption of a thermodynamic transition are shown to be invalid. Various molecular processes responsible for a thermodynamic transition are discussed and it is shown that the general mechanism of ``hindered'' rotation (changes in rotational configuration) is the most likely.
点击下载:
PDF
(479KB)
返 回