The tumbling or flow-aligning nature of nematics as predicted from the Slightly Bending Rod molecular model
作者:
F. Greco,
G. Marrucci,
期刊:
Liquid Crystals
(Taylor Available online 1997)
卷期:
Volume 22,
issue 1
页码: 11-16
ISSN:0267-8292
年代: 1997
DOI:10.1080/026782997209612
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Existing calculations of the Leslie coefficients for rigid rods endowed with the Maier-Saupe potential are here extended to investigate the consequences of relaxing the constraint of a complete molecular rigidity. In particular, the recently proposed model of the Slightly Bending Rod (SBR) is used to calculate the ratio alpha3/alpha2, the sign of which controls whether the nematic is of the tumbling or flow-aligning type. The results show that SBRs are more prone to tumbling than fully rigid rods. The flow-aligning to tumbling transition, which takes place by increasing the order parameter (e.g. by decreasing the temperature) is shifted, for SBRs, to a smaller value of the order parameter.
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