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The tumbling or flow-aligning nature of nematics as predicted from the Slightly Bending Rod molecular model

 

作者: F. Greco,   G. Marrucci,  

 

期刊: Liquid Crystals  (Taylor Available online 1997)
卷期: Volume 22, issue 1  

页码: 11-16

 

ISSN:0267-8292

 

年代: 1997

 

DOI:10.1080/026782997209612

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Existing calculations of the Leslie coefficients for rigid rods endowed with the Maier-Saupe potential are here extended to investigate the consequences of relaxing the constraint of a complete molecular rigidity. In particular, the recently proposed model of the Slightly Bending Rod (SBR) is used to calculate the ratio alpha3/alpha2, the sign of which controls whether the nematic is of the tumbling or flow-aligning type. The results show that SBRs are more prone to tumbling than fully rigid rods. The flow-aligning to tumbling transition, which takes place by increasing the order parameter (e.g. by decreasing the temperature) is shifted, for SBRs, to a smaller value of the order parameter.

 

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