A molecular model for the smectic B phase. The stabilized molecular rotor
作者:
K. Toriyam,
D.A. Dunmur,
期刊:
Liquid Crystals
(Taylor Available online 1993)
卷期:
Volume 13,
issue 6
页码: 797-810
ISSN:0267-8292
年代: 1993
DOI:10.1080/02678299308027294
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Transition temperatures and smectic B mesophase ranges are examined for a number of homologous series, and some general rules are proposed that relate the smectic B phase behaviour to molecular structure. A mechanical model is developed for the crystal and hexatic smectic B phases, based on the dynamics of rigid or elastic rotors, which suggests two possible types of behaviour. It is found that such predicted behaviour is observed for particular series, but in general the smectic B phase characteristics of homologous series may be between the limits established for the model.
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