Kinetic Study of End-Group Stabilization in Hydrocellulose by Hydrogen Sulfide
作者:
VincentL. Chiang,
KyostiV. Sarkanen,
期刊:
Journal of Wood Chemistry and Technology
(Taylor Available online 1984)
卷期:
Volume 4,
issue 1
页码: 1-18
ISSN:0277-3813
年代: 1984
DOI:10.1080/02773818408062280
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The rate of stabilization of hydrocellulose and glucose against alkaline degradation by hydrogen sulfide was studied as a function of pH and H2S-concentration. The rate of this reaction increases to a maximum with an increase in pH from 3.5 to 6.3. The maximum rate is significantly enhanced by the presence of ammonia base. With increasing H2S-concentration, the stabilization rate increases in a sigmoidal manner. It is demonstrated that this kinetic pattern is in full accordance with the reaction mechanism proposed by Procter involving conversion to a thioalditol via a gem-dithiol intermediate.
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