Reactive sputtering of InP in N2and N2/O2plasmas
作者:
C. S. Sundararaman,
H. Lafontaine,
S. Poulin,
A. Mouton,
J. F. Currie,
期刊:
Journal of Vacuum Science&Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena
(AIP Available online 1991)
卷期:
Volume 9,
issue 3
页码: 1433-1439
ISSN:1071-1023
年代: 1991
DOI:10.1116/1.585446
出版商: American Vacuum Society
关键词: INDIUM PHOSPHIDES;SPUTTERING;NITROGEN;OXYGEN;PLASMA;ETCHING;SURFACE REACTIONS
数据来源: AIP
摘要:
The plasma etching of InP using nontoxic, fluorocarbon free, N2and N2/O2mixtures has been demonstrated. The etch rates as a function of pressure, power, and O2content have been studied. Reactive sputtering appears to be the principal etching mechanism for both plasmas. These plasmas react with the InP substrate forming In2O3, InPO4and probably nitride and oxynitrides of indium. N+2and N+ions are the dominant sputtering species in the N2plasma, while addition of small quantities of O2(<2%) to the plasma appears to promote the formation of heavier ions like NO+and NO+2and easily sputterable NO compounds thereby dramatically increasing the etch rates. At higher O2contents (≥4%) strong surface oxidation and formation of compounds containing the NO2radical limit the sputtering rate. Both gas mixtures exhibit low etch rates but form very smooth surfaces.
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