首页   按字顺浏览 期刊浏览 卷期浏览 The Electrochemical Behavior of Bunte Salts
The Electrochemical Behavior of Bunte Salts

 

作者: Andrzej Czerwiński,   Andrzej Orzeszko,   Zygmunt Kazimierczuk,   Roberto Marassi,   Silvia Zamponi,  

 

期刊: Analytical Letters  （Taylor Available online 1997）
卷期: Volume 30, issue 13  

页码: 2391-2408

 

ISSN:0003-2719

 

年代: 1997

 

DOI:10.1080/00032719708001750

 

出版商: Taylor & Francis Group

 

关键词: Bunte salts;platinum electrode;gold electrode;disulfide;electrosynthesis;Bunte salts polymerization

 

数据来源: Taylor

 

摘要:

A comparative cyclic voltammetric study of the Bunte salts adsorption and oxidation of the electrode reaction products on gold and platinum electrodes was performed. These were irreversibly adsorbed on both metals, and were oxidized to disulfides (on gold in basic solution) and in the anodic range of platinum electrode potentials to form water soluble sulfates. Also Bunte salts were oxidized directly from the bulk of solution. Platinum was found to show stronger (than gold) electrocatalytic properties to adsorb and oxidize the electrode reaction products of Bunte salts

 

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