Mesomorphic properties and magnetic behaviour of di-(5-substituted-salicylidene)ethylenediaminato cobalt(II) complexes
作者:
R. Paschke,
S. Diele,
I. Letko,
A. Wiegeleben,
G. Pelzl,
K. Griesar,
M. Athanassopoulou,
W. Haase,
期刊:
Liquid Crystals
(Taylor Available online 1995)
卷期:
Volume 18,
issue 3
页码: 451-456
ISSN:0267-8292
年代: 1995
DOI:10.1080/02678299508036644
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The result of optical X-ray, DSC and magnetic susceptibility studies of new Co(II) metallomesogens are reported. The di-(5-substituted-salicylidene)ethylenediaminato cobalt(II) complexes exhibit broad range Saphases. A comparison with corresponding copper(II) and nickel(II) complexes leads to conclusions about how the properties are influenced by the metal atom. Cobalt(II) complexes of this kind form different modifications which are either active or inactive against oxygen. The conversion process (inactive-active) is monitored by time dependent X-ray diffractometric measurements.
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