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Molecular Weight Dependency of Rheological Characteristics of Linear Low Density Polyethylene

 

作者: D. Acierno,   A. Brancaccio,   D. Curto,   F. P. La Mantia,   A. Valenza,  

 

期刊: Journal of Rheology  (AIP Available online 1985)
卷期: Volume 29, issue 3  

页码: 323-334

 

ISSN:0148-6055

 

年代: 1985

 

DOI:10.1122/1.549793

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

Five samples of linear low density polyethylene, polymerized withl‐butene as comonomer and having different molecular weights but similar molecular weight distributions, have been characterized in shear and nonisothermal elongational flow. From the experimental data, generalized relationships have been found for the zero shear viscosity, the shift factors of the whole viscosity curve, the critical shear rate, the melt strength and the breaking‐stretching ratio. It is then possible to predict with very good confidence values for the most important rheological characteristics of any LLDPE of similar polydispersity from the sole knowledge of the weight average molecular weight, in the range of temperature and flow conditions of industrial interest.

 

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