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Halochrome Molekeln. 6. Mitteilung. Spektrophotometrische Untersuchungen zum acidobasischen Verhalten substituierter 6,6‐Diphenyl‐6H‐chromeno[4,3‐b]indolizine und ihrer Aza‐analogen

 

作者: Sigmund Gunzenhauser,   Heinz Balli,  

 

期刊: Helvetica Chimica Acta  (WILEY Available online 1985)
卷期: Volume 68, issue 1  

页码: 64-71

 

ISSN:0018-019X

 

年代: 1985

 

DOI:10.1002/hlca.19850680108

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

Halochromic Molecules. Spectrophotometric Investigation of the Acidobasic Behaviour of Substituted 6,6‐Diphenyl‐6H‐chromeno[4, 3‐b]indolizines and their Aza‐analoguesSubstituted 6,6‐diphenyl‐6H‐chromeno[4,3‐b]indolizines form ring‐opened, intensely coloured (diphenyl)‐indolizinylcarbenium salts with acid. UV/VIS spectra of the coloured salts are discussed on the basis of VEPPPCI calculations. The ϵpH* curves in buffered MeOH/H2O solutions and the pK* values are determined. The title compounds undergo very complex

 

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