Halochrome Molekeln. 6. Mitteilung. Spektrophotometrische Untersuchungen zum acidobasischen Verhalten substituierter 6,6‐Diphenyl‐6H‐chromeno[4,3‐b]indolizine und ihrer Aza‐analogen
作者:
Sigmund Gunzenhauser,
Heinz Balli,
期刊:
Helvetica Chimica Acta
(WILEY Available online 1985)
卷期:
Volume 68,
issue 1
页码: 64-71
ISSN:0018-019X
年代: 1985
DOI:10.1002/hlca.19850680108
出版商: WILEY‐VCH Verlag GmbH
数据来源: WILEY
摘要:
Halochromic Molecules. Spectrophotometric Investigation of the Acidobasic Behaviour of Substituted 6,6‐Diphenyl‐6H‐chromeno[4, 3‐b]indolizines and their Aza‐analoguesSubstituted 6,6‐diphenyl‐6H‐chromeno[4,3‐b]indolizines form ring‐opened, intensely coloured (diphenyl)‐indolizinylcarbenium salts with acid. UV/VIS spectra of the coloured salts are discussed on the basis of VEPPPCI calculations. The ϵpH* curves in buffered MeOH/H2O solutions and the pK* values are determined. The title compounds undergo very complex
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