Nickel/Chromium oxide/Zirconium oxide Catalysts for Hydrogen/Deuterium Isotopic Exchange
作者:
M. M. Abdel-Badei,
A. El-Sharkawi,
M. Abdel-Khalik,
F. Abou El-Nour,
期刊:
Isotopenpraxis Isotopes in Environmental and Health Studies
(Taylor Available online 1990)
卷期:
Volume 26,
issue 7
页码: 336-338
ISSN:0021-1915
年代: 1990
DOI:10.1080/10256019008624322
出版商: Taylor & Francis Group
关键词: catalysts;chromium oxides;deuterium;hydrogen transfer;isotope effects;isotopic exchange;nickel oxides;specific surface area;surfaces;zirconium oxides
数据来源: Taylor
摘要:
Catalysts composed of nickel and promoted with different metal oxides proved to be suitable for H/D isotropic exchange between hydrogen and water vapour. They loss their activity due to water condensation on their surfaces. Several nickel/chromium oxide/zirconium oxide catalysts of different composition were prepared by the coprecipitation technique. The liquid phase activity of these catalysts were followed using the hydrogen peroxide decomposition on their surfaces at different temperatures. The surface characteristics of the examined catalysts were followed by applying the BET method. The results were discussed and lead to the required catalyst composition which resists the water condensation on its surface during operation and has relatively high activity in the vapour phase H/D isotopic exchange reaction between hydrogen and water.
点击下载:
PDF (300KB)
返 回