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Enantioselective synthesis of epoxides via Sharpless epoxidation of alkenylsilanols

 

作者: T. H. Chan,   L. M. Chen,   D. Wang,   L. H. Li,  

 

期刊: Canadian Journal of Chemistry  （NRC Available online 1993）
卷期: Volume 71, issue 1  

页码: 60-67

 

ISSN:0008-4042

 

年代: 1993

 

DOI:10.1139/v93-009

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

Enantioselective synthesis of simple epoxides can be achieved by Sharpless epoxidation of alkenylsilanols followed by protodesilylation of the chiral epoxysilanols. The approach has been applied to the synthesis of frontalin.

 

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