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The second dielectric virial coefficient of asymmetrical polar hard dumb-bell fluids

 

作者: Masaharu Ohba,   Hiroyasu Nomura,  

 

期刊: Molecular Physics  （Taylor Available online 1990）
卷期: Volume 70, issue 4  

页码: 729-733

 

ISSN:0026-8976

 

年代: 1990

 

DOI:10.1080/00268979000102691

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

We have calculated the second dielectric virial coefficientBϵof some asymmetrical polar hard dumb-bell fluids. In the case of molecules with a short bond length, the effect of the asymmetry of molecular shapes is to increaseBϵ. In contrast, for molecules with a long bond length, the effect is to decreaseBϵgradually.

 

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