AbstractThe ring‐retaining products formed from the OH radical‐initiated reactions ofo‐,m‐, andp‐xylene in the presence of NOxhave been identified and their formation yields determined. Experiments were carried out at 298 ± 2 K and in the presence of 740 torr total pressure of air. The products observed, and their yields, were: fromo‐xylene,o‐tolualdehyde, 0.0453; 2‐methylbenzyl nitrate, (0.0135 + 5.5 × 10−17[NO2]); 2,3‐dimethylphenol, 0.097; 3,4‐dimethyl‐phenol, 0.064; 3‐nitro‐o‐xylene, 0.0059; 4‐nitro‐o‐xylene, (0.0111 + 9.9 × 10−17[NO2]); fromm‐xylene,m‐tolualdehyde, 0.0331; 3‐methylbenzyl nitrate, 0.0061; 2,4‐dimethylphenol, 0.099; 2,6‐dimethylphenol, 0.111; 4‐nitro‐m‐xylene, 0.0018; 5‐nitro‐m‐xylene, (0.0032 + 1.6 × 10−17[NO2]); fromp‐xylene,p‐tolualdehyde, 0.0701; 4‐methylbenzyl nitrate, 0.0082; 2,5‐dimethylphenol, 0.188, 2‐nitro‐p‐xylene, (0.0120 + 2.8 × 10−17[NO2]), where the NO2concentration is in molecule cm−3units. The nitro‐xylene data are consistent with our recent product study of the corresponding reactions of benzene and toluene and indicate that under the experimental conditions employed the dimethylhydroxycyclohexadienyl radicals reacted with NO2and not with O2. When combined with literature ring‐cleavage pr