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What Are One-Electron Energies and Electronegativity-Related Parameters?

 

作者: ChristianK. Jørgensen,  

 

期刊: Comments on Inorganic Chemistry  (Taylor Available online 1991)
卷期: Volume 12, issue 2-3  

页码: 139-197

 

ISSN:0260-3594

 

年代: 1991

 

DOI:10.1080/02603599108050601

 

出版商: Taylor & Francis Group

 

关键词: d group characteristics;ionization energy;lanthanide energy levels;oxidation states;Periodic Table;quantum paradoxes;Schrödinger equation;spin-pairing energy

 

数据来源: Taylor

 

摘要:

A singleZ-nucleus, andKelectrons, allow many different, plausible definitions of one-electron energies. The treatment, originally of atomic spectra [of which very high chargesz= (Z - K) now are known], has been extended into chemistry studying a mist of indiscernible electrons around several nuclei. Quantum chemistry has revealed many counterintuitive (verified) consequences, and its Achilles heel is the correlation effect for two-digitZ. The present status of electronegativity, M.O. and inner-shell ionization, stabilization of oxides and of unusual oxidation states, heats of atomization, d and f group characteristics, and spin-pairing energy are reviewed.

 

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