What Are One-Electron Energies and Electronegativity-Related Parameters?
作者:
ChristianK. Jørgensen,
期刊:
Comments on Inorganic Chemistry
(Taylor Available online 1991)
卷期:
Volume 12,
issue 2-3
页码: 139-197
ISSN:0260-3594
年代: 1991
DOI:10.1080/02603599108050601
出版商: Taylor & Francis Group
关键词: d group characteristics;ionization energy;lanthanide energy levels;oxidation states;Periodic Table;quantum paradoxes;Schrödinger equation;spin-pairing energy
数据来源: Taylor
摘要:
A singleZ-nucleus, andKelectrons, allow many different, plausible definitions of one-electron energies. The treatment, originally of atomic spectra [of which very high chargesz= (Z - K) now are known], has been extended into chemistry studying a mist of indiscernible electrons around several nuclei. Quantum chemistry has revealed many counterintuitive (verified) consequences, and its Achilles heel is the correlation effect for two-digitZ. The present status of electronegativity, M.O. and inner-shell ionization, stabilization of oxides and of unusual oxidation states, heats of atomization, d and f group characteristics, and spin-pairing energy are reviewed.
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