Thermostimulated creep in amorphous polyolefins. II
作者:
C. Lacabanne,
D. Chatain,
J.C. Monpagens,
A. Hiltner,
E. Baer,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1978)
卷期:
Volume 15,
issue 4
页码: 519-526
ISSN:0022-2348
年代: 1978
DOI:10.1080/00222347808212271
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The thermostimulated creep of three amorphous polyolefins having the repeating unit ─(CH2)mC(CH3)(C2H5)─, where m = 1, 2, and 3, was investigated from 77° K to 350° K. A broad relaxation process is observed around the glass transition temperature in each polyolefin. The corresponding TSC peaks have been resolved into elementary components with a relaxation time τ obeying a compensation law τ = τcexp {(ΔH/k)[1/T) —(1/Tc)], where Tcand Tcare characteristic of the polyolefin. From the TSC data, we have calculated, the mechanical loss peaks associated with the glass transition and we have compared them with the dielectric loss peaks.
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