Heterogeneous nucleation of organic vapours on a cold substrate
作者:
Hideo Shinagawa,
Kikuo Okuyama,
Yuji Kawamura,
期刊:
The Canadian Journal of Chemical Engineering
(WILEY Available online 1993)
卷期:
Volume 71,
issue 2
页码: 238-243
ISSN:0008-4034
年代: 1993
DOI:10.1002/cjce.5450710210
出版商: Wiley Subscription Services, Inc., A Wiley Company
关键词: heterogeneous nucleation;sublimation;crystal formation;surface nucleation;supersaturation
数据来源: WILEY
摘要:
AbstractThe heterogeneous phase transition of the organic vapours, cyclohexane and p‐xylene, on a cold substrate was observed by cooling the substrate at a slow rate under reduced pressure conditions. Either organic vapour at a vapour pressure lower than 130 Pa formed directly solid crystals but p‐xylene vapour at a higher vapour pressure formed liquid condensates with subsequent formation of solid crystals. The dependence of the critical supersaturation ratios on the critical temperatures and the physical properties of the organic vapours has been clarified by the equation derived on the basis of classical nucleation the
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