Platinum Catalysed Oxidation of Sucrose
作者:
Les A. Edye,
George V. Meehan,
Geoffrey N. Richards,
期刊:
Journal of Carbohydrate Chemistry
(Taylor Available online 1991)
卷期:
Volume 10,
issue 1
页码: 11-23
ISSN:0732-8303
年代: 1991
DOI:10.1080/07328309108543887
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The platinum catalyzed oxidation of sucrose by oxygen has been studied. With platinum on carbon at 100°C and at constant neutral pH, the oxidation is highly specific for the primary hydroxyls at the 6- and 6′-positions of sucrose. There was no evidence of oxidation of the 1′ hydroxyl. The 6,6′-dicarboxysucrose was resistant to attack by invertase. The 6- and 6′-carboxysucroses could not be resolved from each other, but the former component was hydrolysed rapidly by invertase and subsequently the 6′-carboxysucrose was isolated. The13C spectrum of 6-carboxysucrose was then assigned by difference.
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