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A simplified form of Stokes–Robinson equation

 

作者: Chai-Fu Pan,  

 

期刊: Canadian Journal of Chemistry  (NRC Available online 1976)
卷期: Volume 54, issue 1  

页码: 9-11

 

ISSN:0008-4042

 

年代: 1976

 

DOI:10.1139/v76-003

 

出版商: NRC Research Press

 

数据来源: NRC

 

摘要:

In non-associated dilute aqueous electrolyte solutions, the deviation from ideality is principally attributed to the interionic interactions and hydration of ions. Stokes and Robinson combined Bjerrum's thermodynamic treatment of ion–solvent interactions with Debye–Hückel treatment of interionic interactions to obtain a two-parameter equation. In very dilute regions, the Stokes and Robinson's equation reduces to a much simpler form,i.e.Activity coefficients of an electrolyte at lower concentrations, say up to 0.1 m, can be calculated from the equation provided suitable values of &([a-z]+); andhare available. Solutions of hydrogen chloride and sodium chloride were chosen as examples. The results agree with the existing data very satisfactorily.

 

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