首页   按字顺浏览 期刊浏览 卷期浏览 Synthesis and Polymerization of Methyl Trioxane and Dimethyl Trioxane
Synthesis and Polymerization of Methyl Trioxane and Dimethyl Trioxane

 

作者: Akira Shimizu,   Koichiro Hayashi,   Seizo Okamura,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1967）
卷期: Volume 1, issue 4  

页码: 569-579

 

ISSN:0022-233X

 

年代: 1967

 

DOI:10.1080/10601326708053994

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Methyl trioxane and dimethyl trioxane were synthesized by the cotrimerization of formaldehyde and acetaldehyde. The structures of these two compounds were confirmed by elemental analyses, IR spectra, mass spectra, and NMR spectra. The methyl trioxane was able to polymerize by boron trifluoride etherate, giving a polyoxymethylene, but the dimethyl trioxane was hardly polymerized.

 

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