Foam Fractionation of Mercury(ll) Nitro Complexes
作者:
MichaelW. Miller,
GeraldL. Sullivan,
期刊:
Separation Science
(Taylor Available online 1971)
卷期:
Volume 6,
issue 4
页码: 553-558
ISSN:0037-2366
年代: 1971
DOI:10.1080/00372367108056038
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Using a recycle foam separation apparatus, the foam fractionation distribution factor, γ/C, of the anionic metal nitro complexes of mercury(II) with the cationic surfactant, hexadecyltrimethylammonium bromide, was determined. The distribution factor was measured as a function of nitric acid concentration. The maximum occurred at 0.1Nnitric acid, which is in agreement with the anionic ion-exchange column distribution coefficient. Total reflux foam fractionation experiments yielded a 150-fold increase in the enrichment factor with a 20% recovery of the mercury(II) ion.
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