Energy Levels of Asymmetric Rotors: An Improved Computational Procedure
作者:
C.S. C. Chung,
期刊:
Spectroscopy Letters
(Taylor Available online 1973)
卷期:
Volume 6,
issue 10
页码: 617-620
ISSN:0038-7010
年代: 1973
DOI:10.1080/00387017308060851
出版商: Taylor & Francis Group
关键词: Microwave Spectroscopy;Asymmetric Rotor Energy Levels
数据来源: Taylor
摘要:
The microwave band spectra1of asymmetric top molecules have 2J + 1 distinct rotational energy sublevels for each value of rotational quantum nuqber J. Through application of group theory, the statimary states of rigid asymmetric rotors can be classified by the irreducible representations or by the symmetry species of the V(D2) point group (the Four-group). When performing a Wang syrnrnetrizing transformation2on the original energy matrix E(K) where k is the Raj's asymmetry parameter: a new energy matrix E'(K) may be readily obtained.
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