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Energy Levels of Asymmetric Rotors: An Improved Computational Procedure

 

作者: C.S. C. Chung,  

 

期刊: Spectroscopy Letters  (Taylor Available online 1973)
卷期: Volume 6, issue 10  

页码: 617-620

 

ISSN:0038-7010

 

年代: 1973

 

DOI:10.1080/00387017308060851

 

出版商: Taylor & Francis Group

 

关键词: Microwave Spectroscopy;Asymmetric Rotor Energy Levels

 

数据来源: Taylor

 

摘要:

The microwave band spectra1of asymmetric top molecules have 2J + 1 distinct rotational energy sublevels for each value of rotational quantum nuqber J. Through application of group theory, the statimary states of rigid asymmetric rotors can be classified by the irreducible representations or by the symmetry species of the V(D2) point group (the Four-group). When performing a Wang syrnrnetrizing transformation2on the original energy matrix E(K) where k is the Raj's asymmetry parameter: a new energy matrix E'(K) may be readily obtained.

 

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