Thermodynamics and Phase Equilibria in the Sr─Cu─O System
作者:
Ryosuke O. Suzuki,
Petr Bohac,
Ludwig J. Gauckler,
期刊:
Journal of the American Ceramic Society
(WILEY Available online 1992)
卷期:
Volume 75,
issue 10
页码: 2833-2842
ISSN:0002-7820
年代: 1992
DOI:10.1111/j.1151-2916.1992.tb05513.x
出版商: Blackwell Publishing Ltd
数据来源: WILEY
摘要:
Phase equilibria in the SrO─CuO─Cu system were determined at 1173 K from the results of X‐ray diffraction measurements using specimens annealed under low oxygen partial pressure (po2= 0.21–10−8atm). Electromotive force (EMF) measurements using ZrO2solid electrolyte cells were carried out in the ternary phase equilibria. Gibbs free energies for five reactions in the cell electrodes were summarized by equations with linear temperature dependence. The standard free energies of formation for Sr2CuO3, SrCuO2, Sr14Cu24O41, and SrCu2O2were derived. The stability conditions of all oxides are displayed in thep‐T‐xdiagram using
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