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Synthesis and reactivity of 22,23‐methylene‐2,3,17,18‐tetramethyl‐23‐hydro‐1, 19‐[21H,2...
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Synthesis and reactivity of 22,23‐methylene‐2,3,17,18‐tetramethyl‐23‐hydro‐1, 19‐[21H,24H]‐bilindion‐10‐enium trifluoroacetate
作者:
J. A. de Groot,
R. van der Steen,
J. Lugtenburg,
期刊:
Recueil des Travaux Chimiques des Pays‐Bas
(WILEY Available online 1982)
卷期:
Volume 101,
issue 7‐8
页码: 263-266
ISSN:0165-0513
年代: 1982
DOI:10.1002/recl.19821010706
出版商: WILEY‐VCH Verlag
数据来源: WILEY
摘要:
AbstractThe biliverdinium salt 1 has been prepared in high yield and its behaviour towards nucleophiles studied. The reactions have been found to occur selectively on the central carbon atom 10 and to lead to bilirubin systems. In addition, the photoisomerisation of the bilirubin model compound 5, prepared from 1, has been investigated.
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