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Synthesis and reactivity of 22,23‐methylene‐2,3,17,18‐tetramethyl‐23‐hydro‐1, 19‐[21H,24H]‐bilindion‐10‐enium trifluoroacetate

 

作者: J. A. de Groot,   R. van der Steen,   J. Lugtenburg,  

 

期刊: Recueil des Travaux Chimiques des Pays‐Bas  (WILEY Available online 1982)
卷期: Volume 101, issue 7‐8  

页码: 263-266

 

ISSN:0165-0513

 

年代: 1982

 

DOI:10.1002/recl.19821010706

 

出版商: WILEY‐VCH Verlag

 

数据来源: WILEY

 

摘要:

AbstractThe biliverdinium salt 1 has been prepared in high yield and its behaviour towards nucleophiles studied. The reactions have been found to occur selectively on the central carbon atom 10 and to lead to bilirubin systems. In addition, the photoisomerisation of the bilirubin model compound 5, prepared from 1, has been investigated.

 

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