Simultaneous Treatment of Vapor Pressures and Related Thermal Data Between the Triple and Normal Boiling Temperatures forn‐Alkanes C5–C20
作者:
Kveˇtoslav Ru˚zˇicˇka,
Vladimi´r Majer,
期刊:
Journal of Physical & Chemical Reference Data
(AIP Available online 1994)
卷期:
Volume 23,
issue 1
页码: 1-39
ISSN:0047-2689
年代: 1994
DOI:10.1063/1.555942
出版商: AIP
数据来源: AIP
摘要:
Experimental vapor pressures, calorimetric enthalpies of vaporization and differences between the heat capacities of the ideal gas and the liquid forn‐alkanes C5to C20between the triple and normal boiling temperatures have been treated simultaneously. Attention was focused particularly on the region of low pressures where vapor pressure data are scarce and subject to important systematic errors. The reliability and consistency of data fro different sources was evaluated and the three parameter Cox equation was used to correlate simultaneously as a function of temperature the selected values of different properties. The recommended vapor pressures and thermal data resulting from this procedure are mutually consistent over the homologous series and present a considerable refinement particularly at lower pressures.
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