Average Configuration of Finite Polymer with Excluded Volume Interaction
作者:
Chung Yuan Mou,
期刊:
Journal of the Chinese Chemical Society
(WILEY Available online 1984)
卷期:
Volume 31,
issue 1
页码: 1-8
ISSN:0009-4536
年代: 1984
DOI:10.1002/jccs.198400001
出版商: WILEY‐VCH Verlag
关键词: Polymer configuration
数据来源: WILEY
摘要:
AbstractA quasi‐thermodynamic model for expansion of polymer configuration in solution is investigated. The model is based on Gaussian distribution of segments and mean field theory of polymer solution. An in‐homogeneous contribution to the free energy of solution is proposed. It arises from the nonhomogeneous distribution of polymer segements. This effects makes the expansion factor α to be larger than those without the effect considered. Some numerical consequence for the case Polydimethylsiloxane+cyclohexane solution is calculated. Our theory predicts a larger value a than the case without inhomogeneous effect being considered. The difference becomes less significant at higher molecular we
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