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Virial coefficients of hard convex molecules in two dimensions

 

作者: Maurice Rigby,  

 

期刊: Molecular Physics  (Taylor Available online 1993)
卷期: Volume 78, issue 1  

页码: 21-27

 

ISSN:0026-8976

 

年代: 1993

 

DOI:10.1080/00268979300100031

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Third, fourth and fifth virial coefficients are reported for isotropic 2-dimensional fluids of hard convex molecules of elliptical and spherocylindrical shapes, covering a wide range of elongations. Similar results are also included for hard lines of unit length, to give values in the limit of extreme elongation. Comparison with recent results forB3andB4confirms their values. BothB4andB5become negative when the elongation is large. ForB4this occurs only at very extreme elongations, around 50:1 for ellipses, and an even larger value for spherocylinders, whileB5becomes negative at much lower elongations, around 6:1 for ellipses.

 

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