首页   按字顺浏览 期刊浏览 卷期浏览 A method to improve the nonrepetitive acquisition of transient absorption spectra with ...
A method to improve the nonrepetitive acquisition of transient absorption spectra with an intensified charge-coupled device camera

 

作者: G. Baldacchino,   B. Hickel,  

 

期刊: Review of Scientific Instruments  (AIP Available online 1998)
卷期: Volume 69, issue 4  

页码: 1605-1609

 

ISSN:0034-6748

 

年代: 1998

 

DOI:10.1063/1.1148816

 

出版商: AIP

 

数据来源: AIP

 

摘要:

This article describes in detail a new method of data acquisition using an intensified charge coupled device (CCD) camera coupled with a monochromator as a time-resolved absorption spectrometer. The method is based on a full image transfer taking full advantage of the dynamic range of the CCD. The accumulation of several lines of the matrix is then limited by the 32-bit range of the computer calculation. The absorbance characteristics are a good signal-to-noise ratio and a large linearity domain (absorbances between 0.05 and 0.6) in the visible range (350–700 nm) with temporal gates less than 100 ns. The time-resolved absorption spectra obtained for two transient species in aqueous solution [CO3−and(SCN)2−] are presented and are in good agreement with those considered as reference and obtained with a multistep method with a classical monochromator-photomultiplier device. ©1998 American Institute of Physics.

 

点击下载:  PDF (97KB)



返 回