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Deacetylation Regioselective De Glycals

 

作者: Salah Bouhroum,   Joseph A. Grondin,   Stephan Houdier,   Hassan Lazrek,   Mohamed Rhazi,   Abdelouahad Tolaimate,   Philippe J.A. Vottéro,  

 

期刊: Journal of Carbohydrate Chemistry  (Taylor Available online 1991)
卷期: Volume 10, issue 3  

页码: 309-314

 

ISSN:0732-8303

 

年代: 1991

 

DOI:10.1080/07328309108543910

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Hydrazine acetate is shown to effect selective deacetylation on peracetylated glycals like D-xylal, D-glucal, D-galactal and L-rhamnal. It is demonstrated that the observed selectivity on the -4 position cannot be explained by acetyl migration during the reaction.

 

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