首页   按字顺浏览 期刊浏览 卷期浏览 Quenching Rate and Quenched‐In Lattice Vacancies in Gold
Quenching Rate and Quenched‐In Lattice Vacancies in Gold

 

作者: T. Mori,   M. Meshii,   J. W. Kauffman,  

 

期刊: Journal of Applied Physics  (AIP Available online 1962)
卷期: Volume 33, issue 9  

页码: 2776-2780

 

ISSN:0021-8979

 

年代: 1962

 

DOI:10.1063/1.1702548

 

出版商: AIP

 

数据来源: AIP

 

摘要:

The quenched‐in resistivity in gold was measured for cooling rates from 104to 105°C/sec. The quenched‐in resistivity increases considerably with increasing cooling rate and depends strongly on the quenching temperature over much of the range investigated; for example, for a cooling rate of 20 000°C/sec about 12% of the residual resistivity recovers during the quenching process for a quench from 700°C and about 20% recovers for a quench from 800°C. For the lower quenching temperatures the quenched‐in resistivity appears to approach saturation at the fastest quenching rates obtained. A linear relation between the logarithm of quenched‐in resistivity and the reciprocal of quenching rate was observed. This allowed linear extrapolation to infinite quenching rate. The quenched‐in resistivity &rgr;∞obtained by extrapolating to infinite rate, is expressed by &rgr;∞=&rgr;0exp(−Hf/kT), where &rgr;0=5.0×10−4&OHgr;‐cm and the formation enthalpy,Hf=0.97 eV. Assuming &rgr;∞corresponds to single vacancies rather than clusters, measurements of the length change of the quenched specimens and using Tewordt's result that a vacancy has 0.47 atomic volume, the following constants were obtained: The resistivity of 1 at. % of vacancies, 1.7×10−6&OHgr;‐cm; the entropy of formation of a vacancy, 0.95×10−4eV/°K; and the fractional concentration at the melting point, 6.4×10−4.

 

点击下载:  PDF (406KB)



返 回